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Demolition Expert (Fallout Supplement)
From D&D Wiki
For characters that like to blow things up, there is nothing better than this feat. Explosives used by this character do more damage and hit more often.
Prerequisite: Level 3, 4 ranks in Demolitions
Benefit: Grenades and Explosives do 1d6 more damage, +2 on all Demolition skill checks.